2. Alfredo Di Stefano – Real Madrid
El Classico goals: 18
A player with a fantastic goal record all-round – not just against Barcelona. However, his name somewhat sticks in the craw of Madrid’s greatest rivals as he was originally meant to sign for them, only for Real to poach him at the last minute. An astonishing 14 of his goals came against Barca in the league, whist a further four were bagged during both domestic and European cup campaigns.